Keith J. Stevenson

stevenson@cm.utexas.edu
Analytical Chemistry

Assistant Professor, Faculty
Fellow, Jack S. Josey Professorship in Energy Studies

keith
Course Web Site
CH 376K- Spring 2005

Contact Information
WEL 3.416
Office Phone: 232-9160
Fax: 471-8696

Education
B.A., University of Puget Sound (1989);
Ph.D., University of Utah (1997);
Postdoctoral Fellow, Northwestern University (1997-2000)

Awards
NSF Career Award (2002); CSGS New Scholar Award (2004); SEAC Young Investigator Award (2006)

Affiliations
Center for Nano- and Molecular Science and Technology; Texas Material Institute

Analytical Chemistry, Electrochemistry, and Surface Chemistry
Our research is aimed at understanding and controlling the kinetics and energetics of reactions occurring at scientifically interesting and technologically relevant solid/liquid interfaces. Driving our fundamental interest is the need to comprehend the intricate relationships between mass transport, surface reactivity and interfacial structure. Information of this kind is useful for the design and optimization of superior chemical process technologies associated with the areas of chemical sensing, energy storage/conversion, separations, photonics, microelectronics, and device miniaturization.

"Reactive Imaging" of Nanostructured Materials for Advanced Power Sources
This project involves the development of novel optical and scanning probe imaging strategies for studying interfacial ion transfer reactions. We hope to understand mechanistic issues associated with electrochemically-stimulated intercalation behavior at mesoporous metal oxide electrode/solution interfaces for fabrication of superior energy materials (e.g., batteries).

Development of Chemically-Responsive Materials, Sensors, and Photonic Devices
This project is directed toward the rational preparation and assembly of nanostructured materials (mesoporous, colloidal, sorptive or framework solids) for use in developing low-cost and selective chemical sensing methodologies. These materials could prove useful as novel photonic devices or function as active elements for chemo-responsive and electroactive sensors and actuators.

Interrogation of Nucleation, Growth, and Corrosion Events at Metallic Thin Films
This project focuses on the study of metallic thin films commonly utilized in the manufacture of microelectronic devices. We hope to better elucidate film growth and stability processes in relation to microstructure (e.g., defects, impurities, grain boundaries) and interfacial microenvironment (e.g., role of oxidizers and passivators) for development of spatially-controlled electroforming techniques (deposition and etching) for fabrication of nano-features and microstructures.

Representative Publications

Maldonado, S.; Stevenson, K. J. “Influence of Nitrogen Doping on Oxygen Electrocatalysis at Carbon Nanofiber Electrodes,” J. Phys. Chem. B, 2005, 109(10), 4707

McEvoy, T. M.; Stevenson, “Spatially-Resolved Imaging of Inhomogeneous Ion/Charge Transfer Behavior in Polymorphous MoO3. I. Correlation of Localized Structural, Electronic, and Chemical Properties Using Conductive Probe AFM and Raman Microscopy; Langmuir, 2005, 21(8), 3521

Maldonado, S.; Stevenson, K. J. "Direct Preparation of Carbon Nanofiber Electrodes Via Pyrolysis of Iron(II) Phthalocyanine: Electrocatalytic Aspects for Oxygen Reduction" J. Phys. Chem. B, 2004, 108(31), 11375

McEvoy, T. M.; Stevenson, K. J. "Spatially-Resolved Measurement of Inhomogeneous Electroninsertion/Electrocoloration in Polycrystalline Molybdenum Oxide Thin Films Via Chronoabsorptometric Imaging" J. Am. Chem. Soc., 2003, 125, 8438