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Marv Hackert, Pasha Golubkov, Steve Ernst, Don Carroll
=
;
Natalie Potts =
;
Rakhi Dasgupta
=
; &n=
bsp; =
; &n=
bsp; =
; &n=
bsp;
Jeff Almrud
![](3D"slide0140_image002.jpg")
Fu=
nding:
NI=
H /
Welch Fdtn
![](3D"slide0140_image004.gif")
![](3D"slide0140_image006.gif")
![](3D"slide0140_image008.jpg")
Hackert Research Group
Structural molecular
biology, protein crystallography, and biochemistry
=
=
CHMI 1 PHFIVECSDNIREEADLPGLFAKVNPTLAATGIFPLAGIRSRVHWVDTWQMADGQHDY=
AFVHMTLK..-125
MIF
1 PMFIVNTNVP_RASVPEGFLSELTQQLAQATGK_PAQYIAVHVVPDQLMTFSGTNDPCALCSLHSIGK..-114
4-OT–
(Tautomerase/MIF Superfamily)
- wi=
th
Professor Chris Whitman (Pharmacy)
![](3D"slide0046_image010.jpg")
=
=
Chr=
istian
P. Whitman
![](3D"slide0046_image012.jpg")
![](3D"slide0046_image014.jpg")
![](3D"slide0046_image016.jpg")
=
=
=
A)
=
=
=
B)
=
=
=
C)
Ref: Taylor, A.B., Czerwinski, R.M., Johnson, W.H., Whitman, C.P=
.,
and Hackert, M.L., "Crystal Structure of 4-Oxalocrotonate Tautomerase
Inactivated by 2-Oxo-3-pentynotate at 2.4Å resolution:
Analysis and Implications for the Mechanism of Inactivation and
Catalysis" Biochemistry, 37, 14692-14700 (1998).
![](3D"slide0046_image017.gif")
![](3D"slide0046_image018.gif")
PCALCSLHSIGK......=
..
![](3D"slide0046_image019.gif")
![](3D"slide0145_image021.jpg")
![](3D"slide0145_image023.jpg")
![](3D"slide0145_image025.gif")
4-OT– (Tautomerase/MIF
Superfamily)
- wi=
th
Professor Chris Whitman (Pharmacy)
![](3D"slide0012_image027.jpg")
![](3D"slide0012_image028.gif")
(The “Mother” Enzyme)
(Pro-1)
![](3D"slide0037_image030.jpg")
![](3D"slide0037_image032.jpg")
Active sites at interface
of
two dimers
![](3D"slide0037_image033.gif")
![](3D"slide0037_image034.gif")
![](3D"slide0037_image035.gif")
2-oxo-3-pentynoate=
![](3D"slide0037_image037.gif")
![](3D"slide0037_image039.gif")
![](3D"slide0037_image040.gif")
4-OT
Amino-terminal proline general base cataly=
st
![](3D"slide0060_image042.jpg")
General acid-b=
ase
catalysis
? General Acid =
;
X-ray Arg 39”
? Binding of –COO =
;
X-ray Arg 39” / Arg11’=
;
? Low pKa of Pro 1 =
;
Phe
50 / Arg 39
![](3D"slide0041_image043.gif")
![](3D"slide0041_image045.gif")
![](3D"slide0041_image046.gif")
![](3D"slide0041_image047.gif")
![](3D"slide0041_image048.gif")
![](3D"slide0041_image049.gif")
![](3D"slide0041_image050.gif")
![](3D"slide0041_image051.gif")
R39
P1
R11
Five Subfamilies within the 4-OT Superfamily of Enzy=
mes.
Probable Hexamers bbbbbbb =
;
hhhhhhhhhhhhhhhhhhh bbbbbbb bbb bbb hhh1. + =
;
+ &nb=
sp;
+ &nb=
sp;
+ +=
+ + +
Pseudomonas putida XylHa PIAQIHIL-E----GR---SDEQKETLIREVSEAISRSLDAPLTSVRVIIT=
EMAKGH-FGIGG ELASKVRR
Pseudomonas stutzeri NahJ PIAQIHIL-E--=
--GR---SDEQKETLIREVSEAI=
SRSLDAPLTSVRVIIT=
EMPKVH-FGIGG ESAKAIGR
Pseudomonas sp. DmpI PIAQLYII-E----GR---TDEQKETLIRQVSEAMANSLDAPLERVRVLIT=
EMPKNH-FGIGG EPASKVRR
Pseudomonas putida NahJ PIAQLYIL-E--=
--GR---SDEQKETLIREVSEAM=
SRSLDAPIERVRVIIT=
EMPKNH-FGIGG EPASKLNR
Pseudomonas putida TdnL PFAQIYMI-E--=
--GR---TEAQKKAVIEKVSQAL=
VEATGAPMANVRVWIQ=
EVPKEN-WGIAG VSAKELGR
Comamonas testosteroni AphI PFAQIYML-E--=
--GR---SEEQKKAVIEKVTRAL=
VEAVGAPSANVRVWIH=
DVPKEN-WGIAG VSAKELGR
Ralstonia solanacearum Rsp0893 PLIQVTLI-E--=
--GR---TMEAKAALIGSLTQAA=
VATLGAPRESVRVIIQ=
EVPAAH-WGVAG VPKSAAKEPPR=
DSKA
Novosphingobium aromaticivorans XylH PIIEVNLF-E--=
--GR---PPEAKERLIKALTDAA=
IDAIGAPRESVRVILR=
EMAPAH-FAVGG LSFAAKAAAAA=
AAQPRVEEDWSNEN
Sphingomonas chungbukensis PhnL PIIEVNLL-E--=
--GR---PPEAKERLIRALTDAA=
IGAIGAPRESVRVILR=
EMDPAH-FAVGG VSFAAKAAAAQ=
PRVEEDWSNEA
2. Staphylococcus aureus SAV1363 =
PIVNVKLL-E--=
--GR---SDEQLKNL=
VSEVTDAVEKTTGANRQAIHVVIE=
EMKPNH-YGVAG VRKSDQ
Bacillus halodurans BH3814 PIVTVKFL-E--=
--GR---SDEQKRALVERVTEAV=
AETIQANPEKIHVVLE=
EMRKDH-YGVAG KRISDQ
Listeria innocua Lin2709
PFVTIQFL-E--=
--GR---SDDQKKALVSEVTDVV=
SKNLKAPKENIHVILE=
EMKKTD-YGVGG VRKSDI
Listeria monocytogenes Lmo2564 PFVTIQFL-E--=
--GR---TDDQKKALVSEVTEVV=
SKNLKAPKENIHVILE=
EMKKTD-YGVGG VRKSDI
Streptococcus pyogenes Spy1139 PFVTIDLF-E--=
--GR---SQEQKNQLAREVTEVV=
SRIAKAPKENIHVFIN=
DMPEGT-YYPQ<=
span
style=3D'font-family:"Courier New";mso-ascii-font-family:"Courier New";
mso-bidi-font-family:"Courier New";mso-hansi-font-family:"Courier New";
font-size:33%;color:black'>GEMKQKS
Streptococcus thermophilus 4-OT PFVKIDLF-E--=
--GR---SEEQKIELAREVTEVV=
SRVAKAPKEAIHVFIN=
DMPEGT-YYPH<=
span
style=3D'font-family:"Courier New";mso-ascii-font-family:"Courier New";
mso-bidi-font-family:"Courier New";mso-hansi-font-family:"Courier New";
font-size:33%;color:black'>GEMKKKN
Streptococcus pneumoniae SP1017 PFVRIDLF-E--=
--GR---TLEQKKALAKEVTEAV=
VRNTGAPQSAVHVIIN=
DMPEGT-YFPQ<=
span
style=3D'font-family:"Courier New";mso-ascii-font-family:"Courier New";
mso-bidi-font-family:"Courier New";mso-hansi-font-family:"Courier New";
font-size:33%;color:black'>GEMRTK
8Lactococ=
cus
lactis XylH PYVHVELF-E--=
--GR---TVEQKAIIAKEITESI=
SKHAGAPTSAIHVIFN=
DLPEGM-LYQG<=
/span>GEMKKKK
Bacillus subtilis YwhB PYVTVKML-E----GR---TDEQKRNLVEKVTEAVKETTGASEEKIVVFIEEMRKDH-YAVA<=
span
style=3D'font-family:"Courier New";mso-ascii-font-family:"Courier New";
mso-bidi-font-family:"Courier New";mso-hansi-font-family:"Courier New";
font-size:33%;color:black'>GKRLSDME
3.
Helicobacter pylori HP0924 PFINIKLVPE--NGGP---TNEQKQQLIEGVSDLM=
VKVLNKNKASIVVIID<=
/span>EVDSNN-YGLGG ESVHHLRQKN =
Campylobacter jejuni Cj1255 PFVNIRITKE--=
NGEP---TTEQKQELIAGVTDLL=
AKVLNKNKSSTVVIID<=
/span>EIDTDN-YGLGG KSITQARKEKS=
Neisseria meningitidis NMB1474 PYVNIKVTGG--=
KEAP---TAAQKAELIGGVTELL=
ARVLGKNPETTVVVID<=
/span>EVDTDN-WGIGG KSVSERRKEGR=
Yersinia pestis YPO3989
PYVNIKITREG-=
------ATAEQKKQLIAGVTQLL=
VDTLGKNPATTVVVID<=
/span>EVETDN-WGIGG RSVTDLRQSS =
Erwinia chrysanthemi YkdK PFVNIRITKDG-=
------VTAEQKKQLIAGVTQLL=
VDTLGKNPATTVVIID<=
/span>EVETDN-WGIGG ESVTERRQQAH=
DRKHNV
Campylobacter jejuni Cj0270 PLVNIKLAKPS-=
------LSKEQKAELIADITELL=
STKYNKSKERVVVVLE<=
/span>DVENYD-IGFGG ESVEAIKAKAS=
K
Caulobacter crescentus CC2975 PYVNIQVTREG-=
------VTREQKARLIDGVTTLL=
AEVLGKDPNTTFVVIE<=
/span>EVALEN-WGVGG LPVEAYRARKR=
PAAT
Sinorhizobium meliloti SMb20209
PIVTVQVTREGS=
APGRNSVTAEEKAAIIKGVSEVL=
LDVLNKPLESTYVVIE<=
/span>EVELDN-WGWGG FPTVQFRRQRA=
ETARS
4.
Archaeoglobus fulgidus AF0669 PVLIVYGP---------KLDVGKKREFVERLTSVA=
AEIYGMDRSAITILIHEPPAEN-VGVGG KLIADRERE <=
span
style=3D'mso-tab-count:2;width:10.93%'>
M. thermoautotrophicum MTH1606 PVIQINCN----=
-----ELTREKKRELVKRITEVS=
SEIMGLPESTITVLIREFPPEM-WGLEVHSSVTGSE=
WFLMGVSPR
Streptomyces coelicolor SCD31.07
PFAHFKVP----=
---AGTLSAEDKKKIVERTTDLY=
AEIYGERARPTTVVLVDEVPD=
GGWGVAGNVLTAAMLNGD=
G
Mesorhizobium loti msl4326
PFVNIRIVKE--=
---VIAADPAGKKADIAKKVTAA=
IMEATGLGNDDVWVVFEEVNARDWYV-<=
span
style=3D'font-family:"Courier New";mso-ascii-font-family:"Courier New";
mso-bidi-font-family:"Courier New";mso-hansi-font-family:"Courier New";
font-size:33%;color:black'>GKTDVETLRKG =
Ralstonia solanacearum RSc0807 PTFHIEMF-E--=
--GR---SADQKRKLVEEVTRVT=
CETLGCAPGAVDIIIAEVKREN-WATGG VLWSEQK
Nostoc PCC7120
asr0697 PFVTVKIA-R--=
--GH---SIEKKRHLVEAITNAL=
VTALDTKPEWITIHIDEFEREN-WAVN<=
span
style=3D'font-family:"Courier New";mso-ascii-font-family:"Courier New";
mso-bidi-font-family:"Courier New";mso-hansi-font-family:"Courier New";
font-size:33%;color:black'>GILHCDRHRGRH=
DETGR
Ralstonia solanacearum RSp1151 PVVRVSWF-E--=
--GK---DAKAKKAVAAEITDSI=
VKHAGTDPKYIYVIFEDIKPSD-WAGA<=
span
style=3D'font-family:"Courier New";mso-ascii-font-family:"Courier New";
mso-bidi-font-family:"Courier New";mso-hansi-font-family:"Courier New";
font-size:33%;color:black'>GRLYGEEPGTP =
Mesorhizobium loti msl1978
PFANIKLP----=
---QAALSKAQKEDLIHRTTAMF=
VDFFGEGVRPTTMVLVEEVADGGYGRADEVFVIPEA=
YRAKE =
Pseudomonas pavonaceae CaaD1 (a)
PMISCDMR-Y--=
--GR---TDEQKRALSAGLLRVI=
SEATGEPRENIFFVIREGSGIN-FVEH<=
span
style=3D'font-family:"Courier New";mso-ascii-font-family:"Courier New";
mso-bidi-font-family:"Courier New";mso-hansi-font-family:"Courier New";
font-size:33%;color:black'>GEHLPDYVPGNA=
NDKALIAKLK
Pseudomonas pavonaceae CaaD2 (b)
PFIECHIA-T--=
--GL---SVARKQQLIRDVIDVT=
NKSIGSDPKIINVLLVEHAEAN-MSIS<=
/span>GRIHGEAASTER=
TPAVS
Probable
Dimers
5. <=
/b>bbbbbbb =
;
hhhhhhhhhhhhhhhhhhh bbb=
bbbb hhhhhhhhhh
=
;
Escherichia coli YdcE PHIDIKCF------PREL-DEQQKAALAADITDVIIRHLNSKDSSISIALQQIQPES-W-QAIWDAEIAP=
QMEALIKKPGYSMNA
Xylella fastidiosa XF1725 PHIIVKIA-E--=
--GR---SQPLKQELADRLAATM=
MDVLGLDSSAVSVAVEDVPMQD-WMQQVYGPDIET=
AGERLLKRPGYGQLASPPEE
<=
/span>
![](3D"slide0026_image052.gif")
![](3D"slide0026_image053.gif")
![](3D"slide0026_image054.gif")
![](3D"slide0026_image055.gif")
![](3D"slide0026_image056.gif")
![](3D"slide0026_image057.gif")
![](3D"slide0026_image058.gif")
![](3D"slide0026_image059.gif")
P R =
;
K R<=
/span>
K <=
/span> E<=
/span> F G
![](3D"slide0026_image060.gif")
X-ray
Crystal Data on 4-OT / 4-OT Homologues
Grp 1. Psuedo. putida <= /i>(R11A) P21212 a =3D 92Å, b =3D 87Å, c =3D 38Å
Grp 2.<= b> Bacillus subtilis = I432 a =3D 142Å, b =3D 142Å, c =3D 142Å
Grp 3.<= b> Helicobacter pylori P21 a =3D 42Å, b =3D 51Å, c =3D 87Å, = b =3D 101o
P41 a =3D 53Å, b =3D 53Å, c =3D 131Å
Grp 4.<= b> Archeoglobus fulgidus <= /i>P3221 a =3D 49Å,&= nbsp; b =3D 49Å, c =3D 119Å, g =3D 120o
Grp 5.<= b> Escherichia coli <= /b>P212121 a =3D 45Å, b =3D 47Å, c =3D 77Å=
Grp 1. Psuedo. putida <= /i>(R11A)
Grp 2.<= b> Bacillus subtilis = I432 a =3D 142Å, b =3D 142Å, c =3D 142Å
Grp 3.<= b> Helicobacter pylori P21 a =3D 42Å, b =3D 51Å, c =3D 87Å, = b =3D 101o
P41 a =3D 53Å, b =3D 53Å, c =3D 131Å
Grp 4.<= b> Archeoglobus fulgidus <= /i>P3221 a =3D 49Å,&= nbsp; b =3D 49Å, c =3D 119Å, g =3D 120o
Grp 5.<= b> Escherichia coli <= /b>P212121 a =3D 45Å, b =3D 47Å, c =3D 77Å=
![](3D"slide0030_image061.jpg")
![](3D"slide0030_image063.jpg")
=
=
=
4-OT hexamer
![](3D"slide0030_image065.jpg")
=
=
=
ywhB hexamer
=
=
=
ydcE dimer
![](3D"slide0128_image067.jpg")
![](3D"slide0128_image068.gif")
![](3D"slide0128_image069.gif")
![](3D"slide0128_image070.jpg")
![](3D"slide0128_image071.gif")
a<=
/div>
3
a<=
/div>
2
3
(ab)
a<=
/div>
3
a<=
/div>
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PowerPoint Presentation
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![](3D"slide0112_image081.jpg")
numSlds )
gSldJumpIdx =3D numSlds;
if ( gSldJumpIdx >=3D 0 ) {
if ( gSldJumpIdx =3D=3D 0 )
gSldJumpIdx =3D 1;
var jumpTo =3D parseInt(gSldJumpIdx);
gSldJump =3D 0; gSldJumpIdx =3D "";
win.GoToSld( parent.GetSldList().mList[jumpTo-1].mSldHref )
}
}
}
function _KDH()
{
if( event.keyCode =3D=3D 8 ) {
event.returnValue =3D 0;
parent.GoToPrevSld();
}
}function DocumentOnClick()
{
if( IsNts() || parent.HideMenu() ) return;
if( ( g_allowAdvOnClick && (window.name=3D=3D"PPTSld") && !parent.IsFrames=
Mode() ) ||
(event && event.keyCode=3D=3D32) ) {
=09
if( g_animUseRuntime && g_animMainSequence && g_animMainSequence.cangonex=
t )
return;
parent.GoToNextSld();
}
}
var g_supportsPPTHTML =3D SupportsPPTHTML(), g_scaleInFrame =3D 1, gId=3D""=
, g_bgSound=3D"",
g_scaleHyperlinks =3D false, g_allowAdvOnClick =3D 1, g_showInBrowser =
=3D 0, gLoopCont =3D 0, gUseSldTimings =3D 1;
var g_showAnimation =3D g_supportsPPTHTML && SupportsPPTAnimation() && ( (w=
indow.name=3D=3D"PPTSld" && !parent.IsFramesMode()) || g_showInBrowser );va=
r g_animManager =3D null;
var g_animUseRuntime =3D false;
var g_animItemsToHide, g_animInteractiveItems, g_animSlideTime;
var g_animMainSequence =3D null;
var ENDSHOW_MESG=3D"End of slide show, click to exit.", SCREEN_MODE=3D"Fram=
es", gIsEndShow=3D0, NUM_VIS_SLDS=3D11, SCRIPT_HREF=3D"script.js", FULLSCR_=
HREF=3D"fullscreen.htm";
var gCurSld =3D gPrevSld =3D 1, g_offset =3D 0, gNtsOpen =3D gHasNts =3D gO=
tlTxtExp =3D 0, gHasNarration =3D 0, gOtlOpen =3D true
window.gPPTHTML=3DSupportsPPTHTML()
var gMainDoc=3Dnew Array(new hrefList("slide0140.htm",1,-1,1),new hrefList(=
"slide0046.htm",1,-1,1),new hrefList("slide0145.htm",1,-1,1),new hrefList("=
slide0012.htm",1,-1,1),new hrefList("slide0037.htm",1,-1,1),new hrefList("s=
lide0060.htm",1,-1,1),new hrefList("slide0041.htm",1,-1,1),new hrefList("sl=
ide0026.htm",1,-1,1),new hrefList("slide0030.htm",1,-1,1),new hrefList("sli=
de0128.htm",1,-1,1),new hrefList("slide0112.htm",1,-1,1));
/*********************************************
Frameset functions
These functions control slide navigation
and state of the frameset.
**********************************************/
function FullScrInit()
{
g_allowAdvOnClick =3D GetCurSld().mAdvOnClk
document.body.style.backgroundColor=3D"black"
document.oncontextmenu=3Dparent._CM;
document.onkeydown =3D _KDH;
document.ondragstart=3DCancel
document.onselectstart=3DCancel
self.focus()
}
function Redirect( frmId )
{=09
var str=3Ddocument.location.hash,idx=3Dstr.indexOf('#'), sId=3DGetSldId()
if(idx>=3D0) str=3Dstr.substr(1);
if( window.name !=3D frmId && ( sId !=3D str) ) {
obj =3D GetObj("Main-File")
window.location.href=3Dobj.href+"#"+sId
return 1
}
return 0
}
var MHTMLPrefix =3D CalculateMHTMLPrefix();=20
function CalculateMHTMLPrefix()
{
if ( document.location.protocol =3D=3D 'mhtml:') {=20
href=3Dnew String(document.location.href)=20
Start=3Dhref.indexOf('!')+1=20
End=3Dhref.lastIndexOf('/')+1=20
if (End < Start)=20
return href.substring(0, Start)=20
else=20
return href.substring(0, End)=20
}
return '';
}
function GetTags(base,tag)
{
if(g_supportsPPTHTML) return base.all.tags(tag);
else return base.getElementsByTagName(tag);
}
function UpdNtsPane(){ if(frames["PPTNts"]) PPTNts.location.replace( MHTMLP=
refix+GetHrefObj( gCurSld ).mNtsHref ) }
function UpdNavPane( sldIndex ){ if(gNavLoaded) PPTNav.UpdNav() }
function UpdOtNavPane(){ if(gOtlNavLoaded) PPTOtlNav.UpdOtlNav() }
function UpdOtlPane(){ if(gOtlLoaded) PPTOtl.UpdOtl() }
function SetHasNts( fVal )
{
if( gHasNts !=3D fVal ) {
gHasNts=3DfVal
UpdNavPane()
}
}
function ToggleOtlText()
{
gOtlTxtExp=3D!gOtlTxtExp
UpdOtlPane()
}
function ClearMedia()
{
// Clear any sounds playing before launching another browser window. Other=
wise,
// in fullscreen mode, you'll continue to hear the sound in the frames mod=
e.
if (PPTSld.pptSound) PPTSld.pptSound.loop =3D 0;
}
function FullScreen()
{=20
if ( PPTSld.g_animUseRuntime )
PPTSld.document.body.pause();
ClearMedia();
var href =3D ( document.location.protocol =3D=3D 'mhtml:') ? FULLSCR_HREF =
: FULLSCR_HREF+"#"+GetHrefObj(gCurSld).mSldHref;
if(PPTNav.event.ctrlKey) {
var w =3D (window.screen.availWidth * 1.0) / 2.0
var h =3D w * (PPTSld.g_origH * 1.0) / PPTSld.g_origW
win =3D window.open( MHTMLPrefix+href,null,"toolbar=3D0,resizable=3D1,top=
=3D0,left=3D0," + "width=3D"+ w + ",height=3D" + h );
if( win.document.body && PPTSld.g_animUseRuntime )
win.document.body.PPTSldFrameset=3Dwindow;
}
else
{
win =3D window.open( MHTMLPrefix+href,null,"fullscreen=3Dyes" );
if( win.document.body && PPTSld.g_animUseRuntime )
win.document.body.PPTSldFrameset=3Dwindow;
}
}
function ToggleVNarration()
{
rObj=3DPPTSld.document.all("NSPlay")
if( rObj && !PPTSld.g_animUseRuntime ) {
if( (rObj.playState =3D=3D 1)||(rObj.playState =3D=3D 0) )
rObj.Play()
else if( rObj.playState =3D=3D 2 )
rObj.Pause()
else
return;
}
else if( PPTSld.g_animUseRuntime )
{
narObj =3D PPTSld.document.all("narrationID")
if( narObj )
narObj.togglePause()
}
}
function GetCurSldNum()
{ =20
obj=3DGetHrefObj(gCurSld)
if( obj.mOrigVis =3D=3D 1 )
return obj.mSldIdx
else =20
return gCurSld
}
function GetNumSlds()
{ =20
if( GetHrefObj(gCurSld).mOrigVis =3D=3D 1 )
return GetSldList().mNumVisSlds;
else
return GetSldList().mList.length
}
function GetSldNum( href )
{
for(ii=3D0; ii 1 )
PopSldList();
else if( !IsFramesMode() ) {
if( gLoopCont )
GoToFirst()
else
EndShow()
}
}
function GoToPrevSld()
{
ii=3DgCurSld-1
if( ii > 0 ) {
obj=3DGetHrefObj(ii)
while ( obj && ( obj.mVis =3D=3D 0 ) && ( ii>0 ) )
obj=3DGetHrefObj(--ii)
if( ii =3D=3D 0 ) ii=3D1
GoToSldNum(ii)
}
}
function GoToFirst(){ GoToSld( GetHrefObj(1).mSldHref ) }
function GoToLast()
{
ii=3DGetSldList().mList.length
if( ii !=3D gCurSld )
GoToSld( GetHrefObj(ii).mSldHref )
}
function GoToSldNum( num )
{
if( PPTSld.event ) PPTSld.event.cancelBubble=3Dtrue
obj =3D GetHrefObj( num )
obj.mVis=3D1
gPrevSld=3DgCurSld
gCurSld =3D num;
PPTSld.location.replace(MHTMLPrefix+obj.mSldHref)
if( IsFramesMode() ) {
UpdNavPane(); UpdOtlPane(); UpdNtsPane()
}
}
function GoToSld( href )
{
if( PPTSld.event ) PPTSld.event.cancelBubble=3Dtrue
GetHrefObj( GetSldNum(href) ).mVis=3D1
PPTSld.location.replace(MHTMLPrefix+href)
}
function SldUpdated( id )
{
if( id =3D=3D GetHrefObj(gCurSld).mSldHref ) return
gPrevSld=3DgCurSld
gCurSld=3DGetSldNum(id)
if( IsFramesMode() ) {
UpdNavPane(); UpdOtlPane(); UpdNtsPane()
}
}
function PrevSldViewed(){ GoToSld( GetHrefObj(gPrevSld).mSldHref ) }
function HasPrevSld() { return ( gIsEndShow || ( gCurSld !=3D 1 && GetHrefO=
bj( gCurSld-1 ).mVis =3D=3D 1 )||( GetCurSldNum() > 1 ) ) }
function HasNextSld() { return (GetCurSldNum() !=3D GetNumSlds()) }
function CloseWindow() {
if( HideMenu() ) return;
=09
var event =3D PPTSld.event;
if( !IsFramesMode() && event && (event.keyCode=3D=3D27 || event.keyCode=3D=
=3D32 || event.type=3D=3D"click" ) )
window.close( self );
CatchNumKeys( self, event );
}
function Unload() { gIsEndShow=3D0; }
function SetupEndShow() {
gIsEndShow=3D1;
PPTSld.document.body.scroll=3D"no";
PPTSld.document.onkeypress=3DCloseWindow;
PPTSld.document.onclick=3DCloseWindow;
PPTSld.document.oncontextmenu=3D_CM;
}
function EndShow()
{
if( IsFramesMode() ) return
if( PPTSld.event ) PPTSld.event.cancelBubble=3Dtrue
doc=3DPPTSld.document
var dir =3D doc.body.dir
if( dir !=3D "rtl" ) dir =3D "ltr";
doc.open()
doc.writeln(' 0) {
PushSldList(sldList,fEnd);
gCurSld =3D 1;
}
else
if( PPTSld.event ) PPTSld.event.cancelBubble=3Dtrue
}
function PushSldList(arr,fEnd) {
var ii =3D gSldStack.length;
gSldStack[ii] =3D new SldList(arr,gCurSld,fEnd);
GoToSld( gSldStack[ii].mList[0].mSldHref );
}
function PopSldList() {
if (gSldStack[gSldStack.length-1].fEndShow)
EndShow()
else {
gCurSld =3D gSldStack[gSldStack.length-1].mCurSld;
gSldStack[gSldStack.length-1] =3D null;
gSldStack.length--;
var sldList =3D gSldStack[gSldStack.length-1];
GoToSld( sldList.mList[gCurSld - 1].mSldHref );
}
}
var custShowList=3Dnew Array();
/*********************************************
Navigation button implementation
There are 2 types of buttons: ImgBtn, TxtBtn
implemented as function objects. They share
a similiar interface so the event handlers
can call SetActive, for example, on a button=20
object without needing to know exactly=20
what type of button it is.
**********************************************/
//----------------------------------
function ImgBtn( oId,bId,w,action )
//----------------------------------
{
var t=3Dthis
t.Perform =3D _IBP
t.SetActive =3D _IBSetA
t.SetInactive=3D _IBSetI
t.SetPressed =3D _IBSetP
t.SetDisabled=3D _IBSetD
t.Enabled =3D _IBSetE
t.ChangeIcon =3D null
t.UserAction =3D action
t.ChgState =3D _IBUI
t.mObjId =3D oId
t.mBorderId=3D bId
t.mWidth =3D w
t.mIsOn =3D t.mCurState =3D 0
}
function _IBSetA()
{
if( this.mIsOn ) {
obj=3Dthis.ChgState( gHiliteClr,gShadowClr,2 )
obj.style.posTop=3D0
}
}
function _IBSetI()
{
if( this.mIsOn ) {
obj=3Dthis.ChgState( gFaceClr,gFaceClr,1 )
obj.style.posTop=3D0=20
}
}
function _IBSetP()
{
if( this.mIsOn ) {
obj=3Dthis.ChgState( gShadowClr,gHiliteClr,2 )
obj.style.posLeft+=3D1; obj.style.posTop+=3D1
}
}
function _IBSetD()
{ =20
obj=3Dthis.ChgState( gFaceClr,gFaceClr,0 )
obj.style.posTop=3D0=20
}
function _IBSetE( state )
{
var t=3Dthis
GetObj( t.mBorderId ).style.visibility=3D"visible"
if( state !=3D t.mIsOn ) {
t.mIsOn=3Dstate
if( state )
t.SetInactive()
else
t.SetDisabled()
}
}
function _IBP()
{
var t=3Dthis
if( t.mIsOn ) {
if( t.UserAction !=3D null )
t.UserAction()
if( t.ChangeIcon ) {
obj=3DGetObj(t.mObjId)
if( t.ChangeIcon() )
obj.style.posLeft=3Dobj.style.posLeft+(t.mCurState-4)*t.mWidth
else
obj.style.posLeft=3Dobj.style.posLeft+(t.mCurState-0)*t.mWidth
}
t.SetActive()
} =20
}
function _IBUI( clr1,clr2,nextState )
{
var t=3Dthis
SetBorder( GetObj( t.mBorderId ),clr1,clr2 )
obj=3DGetObj( t.mObjId )
obj.style.posLeft=3Dobj.style.posLeft+(t.mCurState-nextState)*t.mWidth-obj=
.style.posTop
t.mCurState=3DnextState
return obj
}
//-----------------------------------------
function TxtBtn( oId,oeId,action,chkState )
//-----------------------------------------
{
var t=3Dthis
t.Perform =3D _TBP
t.SetActive =3D _TBSetA
t.SetInactive=3D _TBSetI
t.SetPressed =3D _TBSetP
t.SetDisabled=3D _TBSetD
t.SetEnabled =3D _TBSetE
t.GetState =3D chkState
t.UserAction =3D action
t.ChgState =3D _TBUI
t.mObjId =3D oId
t.m_elementsId=3D oeId
t.mIsOn =3D 1
}
function _TBSetA()
{
var t=3Dthis
if( t.mIsOn && !t.GetState() )
t.ChgState( gHiliteClr,gShadowClr,0,0 )
}
function _TBSetI()
{
var t=3Dthis
if( t.mIsOn && !t.GetState() )
t.ChgState( gFaceClr,gFaceClr,0,0 )
}
function _TBSetP()
{
if( this.mIsOn )
this.ChgState( gShadowClr,gHiliteClr,1,1 )
}
function _TBSetD()
{ =20
this.ChgState( gFaceClr,gFaceClr,0,0 )
this.mIsOn =3D 0
}
function _TBSetE()
{
var t=3Dthis
if( !t.GetState() )
t.ChgState( gFaceClr,gFaceClr,0,0 )
else
t.ChgState( gShadowClr,gHiliteClr,1,1 )
t.mIsOn =3D 1
}
function _TBP()
{
var t=3Dthis
if( t.mIsOn ) {=20
if( t.UserAction !=3D null )
t.UserAction()
if( !t.GetState )
return
if( t.GetState() )
t.SetPressed()
else
t.SetActive()
} =20
}
function _TBUI( clr1,clr2,lOffset,tOffset )
{
SetBorder( GetObj( this.mObjId ),clr1,clr2 )
Offset( GetObj( this.m_elementsId ),lOffset,tOffset )
}
function Offset( obj, top, left ){ obj.style.top=3Dtop; obj.style.left=3Dle=
ft }
function SetBorder( obj, upperLeft, lowerRight )
{
s=3Dobj.style;
s.borderStyle =3D "solid"
s.borderWidth =3D 1=20
s.borderLeftColor =3D s.borderTopColor =3D upperLeft
s.borderBottomColor=3D s.borderRightColor =3D lowerRight
}
function GetBtnObj(){ return gBtnArr[window.event.srcElement.id] }
function BtnOnOver(){ b=3DGetBtnObj(); if( b !=3D null ) b.SetActive() }
function BtnOnDown(){ b=3DGetBtnObj(); if( b !=3D null ) b.SetPressed() }
function BtnOnOut(){ b=3DGetBtnObj(); if( b !=3D null ) b.SetInactive() }
function BtnOnUp()
{
b=3DGetBtnObj()
if( b !=3D null )
b.Perform()
else
Upd()
}
function GetNtsState(){ return parent.gNtsOpen }
function GetOtlState(){ return parent.gOtlOpen }
function GetOtlTxtState(){ return parent.gOtlTxtExp }
function NtsBtnSetFlag( fVal )
{
s=3Ddocument.all.item( this.m_flagId ).style
s.display=3D"none"
if( fVal )
s.display=3D""
else
s.display=3D"none"
}
function _BSetA_Border(){ b =3D gBtnArr[this.mObjId]; if( b !=3D null ) b.S=
etActive() }
function _BSetI_Border(){ b =3D gBtnArr[this.mObjId]; if( b !=3D null ) b.S=
etInactive() }
function _BSetP_Border(){ b =3D gBtnArr[this.mObjId]; if( b !=3D null ) b.S=
etPressed() }
function _BSetA_BorderImg()
{=20
b =3D gBtnArr[this.mBorderId]=20
if( b !=3D null && this.mIsOn && !b.GetState() ) {
obj=3Dthis.ChgState( gHiliteClr,gShadowClr,2 )
obj.style.posTop=3D0
}
}
function _BSetI_BorderImg()
{=20
b =3D gBtnArr[this.mBorderId]
if( b !=3D null && this.mIsOn && !b.GetState() ) {
obj=3Dthis.ChgState( gFaceClr,gFaceClr,1 )
obj.style.posTop=3D0
}
}
var gHiliteClr=3D"THREEDHIGHLIGHT",gShadowClr=3D"THREEDSHADOW",gFaceClr=3D"=
THREEDFACE"
var gBtnArr =3D new Array()
gBtnArr["nb_otl"] =3D new TxtBtn( "nb_otl","nb_otlElem",parent.ToggleOtlPan=
e,GetOtlState )
gBtnArr["nb_otlElem"] =3D new TxtBtn( "nb_otl","nb_otlElem",parent.ToggleOt=
lPane,GetOtlState )
gBtnArr["nb_nts"] =3D new ImgBtn( "nb_nts","nb_ntsBorder",10,parent.ToggleN=
tsPane )
gBtnArr["nb_nts"].SetActive =3D _BSetA_BorderImg;
gBtnArr["nb_nts"].SetInactive =3D _BSetI_BorderImg;
gBtnArr["nb_ntsBorder"] =3D new TxtBtn( "nb_ntsBorder","nb_ntsElem",parent.=
ToggleNtsPane,GetNtsState )
gBtnArr["nb_ntsElem"] =3D new TxtBtn( "nb_ntsBorder","nb_ntsElem",parent.To=
ggleNtsPane,GetNtsState )
gBtnArr["nb_prevBorder"] =3D gBtnArr["nb_prev"]=3D new ImgBtn( "nb_prev","n=
b_prevBorder",30,parent.GoToPrevSld )
gBtnArr["nb_nextBorder"] =3D gBtnArr["nb_next"]=3D new ImgBtn( "nb_next","n=
b_nextBorder",30,parent.GoToNextSld )
gBtnArr["nb_sldshw"]=3D new ImgBtn( "nb_sldshw","nb_sldshwBorder",18,parent=
.FullScreen )
gBtnArr["nb_sldshwBorder"] =3D new TxtBtn( "nb_sldshw","nb_sldshwBorder",pa=
rent.FullScreen,null )
gBtnArr["nb_sldshwBorder"].SetActive =3D _BSetA_Border;
gBtnArr["nb_sldshwBorder"].SetInactive =3D _BSetI_Border;
gBtnArr["nb_sldshwText"] =3D new TxtBtn( "nb_sldshw","nb_sldshwText",parent=
.FullScreen,null )
gBtnArr["nb_sldshwText"].SetActive =3D _BSetA_Border;
gBtnArr["nb_sldshwText"].SetInactive =3D _BSetI_Border;
gBtnArr["nb_voice"] =3D gBtnArr["nb_voiceBorder"] =3D new ImgBtn( "nb_voice=
","nb_voiceBorder",18,parent.ToggleVNarration )
gBtnArr["nb_otlTxtBorder"] =3D gBtnArr["nb_otlTxt"]=3D new ImgBtn( "nb_otlT=
xt","nb_otlTxtBorder",23,parent.ToggleOtlText )
gBtnArr["nb_ntsBorder"].m_flagId=3D "nb_nts"
gBtnArr["nb_ntsBorder"].SetFlag =3D NtsBtnSetFlag
gBtnArr["nb_otlTxt"].ChangeIcon=3D GetOtlTxtState
/*********************************************
Context menu implementation
_CM() is the function that's hooked up to
the oncontextmenu event. Once we're asked to
show the menu, we first build it by creating
DIVs on-the-fly. Then we position it=20
within the screen area so it doesn't get
clipped.
Creating the DIVs using createElement() means
we don't have to write out any extra HTML
into the slide HTML files.
**********************************************/
var sNext=3D"Next",sPrev=3D"Previous",sEnd=3D"End Show",sFont=3D"Arial",sAr=
row=3D"Arrow",sFreeform=3D"Freeform",sRect=3D"Rectangle",sOval=3D"Oval"
function ShowMenu()
{
BuildMenu();
var doc=3DPPTSld.document.body,x=3DPPTSld.event.clientX+doc.scrollLeft,y=
=3DPPTSld.event.clientY+doc.scrollTop
m =3D PPTSld.document.all.item("ctxtmenu")
m.style.pixelLeft=3Dx
if( (x+m.scrollWidth > doc.clientWidth)&&(x-m.scrollWidth > 0) )
m.style.pixelLeft=3Dx-m.scrollWidth
m.style.pixelTop=3Dy
if( (y+m.scrollHeight > doc.clientHeight)&&(y-m.scrollHeight > 0) )
m.style.pixelTop=3Dy-m.scrollHeight
m.style.display=3D""
}
function _CM()
{
if( !parent.IsFullScrMode() ) return;
if(!PPTSld.event.ctrlKey) {
ShowMenu()
return false
} else
HideMenu()
}
function BuildMenu()
{
if( PPTSld.document.all.item("ctxtmenu") ) return
var mObj=3DCreateItem( PPTSld.document.body )
mObj.id=3D"ctxtmenu"
mObj.style.visibility=3D"hidden"
var s=3DmObj.style
s.position=3D"absolute"
s.cursor=3D"default"
s.width=3D"120px"
SetCMBorder(mObj,"menu","black")
var iObj=3DCreateItem( mObj )
SetCMBorder( iObj, "threedhighlight","threedshadow" )
iObj.style.padding=3D2
CreateMenuItem( iObj,sNext,M_GoNextSld,M_True )
CreateMenuItem( iObj,sPrev,M_GoPrevSld,M_HasPrevSld )
=09
CreateSeparator( iObj )
CreateMenuItem( iObj,sEnd,M_End,M_True )
mObj.style.visibility=3D"visible"
}
function Cancel() { window.event.cancelBubble=3Dtrue; window.event.returnVa=
lue=3Dfalse }
function Highlight() { ChangeClr("activecaption","threedhighlight") }
function Deselect() { ChangeClr("threedface","menutext") }
function Perform()
{
e=3DPPTSld.event.srcElement
if( e.type=3D=3D"menuitem" && e.IsActive() )
e.Action()
else
PPTSld.event.cancelBubble=3Dtrue
}
function ChangeClr( bg,clr )
{
e=3DPPTSld.event.srcElement
if( e.type=3D=3D"menuitem" && e.IsActive() ) {
e.style.backgroundColor=3Dbg
e.style.color=3Dclr
}
}
function M_HasPrevSld() { return( parent.HasPrevSld() ) }
function M_GoNextSld() { if( gIsEndShow ) M_End(); else GoToNextSld() }
function M_GoPrevSld() { if( gIsEndShow ) { gIsEndShow=3D0; history.back();=
PPTSld.event.cancelBubble=3Dtrue; } else GoToPrevSld() }
function M_True() { return true }
function M_End() { window.close( self ) }
function CreateMenuItem( node,text,action,eval )
{
var e=3DCreateItem( node )
e.type=3D"menuitem"
e.Action=3Daction
e.IsActive=3Deval
e.innerHTML=3Dtext
if( !e.IsActive() )
e.style.color=3D"threedshadow"
e.onclick=3DPerform
e.onmouseover=3DHighlight
e.onmouseout=3DDeselect
s=3De.style;
s.fontFamily=3DsFont
s.fontSize=3D"9pt"
s.paddingLeft=3D2
}
function CreateSeparator( node )
{
var sObj=3DCreateItem( node )
SetCMBorder(sObj,"menu","menu")
var s=3DsObj.style
s.borderTopColor=3D"threedshadow"
s.borderBottomColor=3D"threedhighlight"
s.height=3D1
s.fontSize=3D"0px"
}
function CreateItem( node )
{
var elem=3DPPTSld.document.createElement("DIV")
node.insertBefore( elem )
return elem
}
function SetCMBorder( o,ltClr,rbClr )
{
var s=3Do.style
s.backgroundColor=3D"menu"
s.borderStyle=3D"solid"
s.borderWidth=3D1
s.borderColor=3DltClr+" "+rbClr+" "+rbClr+" "+ltClr
}
------=_NextPart_01C49113.DF3ED6A0
Content-Location: file:///C:/2D1B8234/Hackert_4OT_04_files/fullscreen.htm
Content-Transfer-Encoding: quoted-printable
Content-Type: text/html; charset="us-ascii"
PowerPoint Presentation
------=_NextPart_01C49113.DF3ED6A0--
6
a<=
/div>
![](3D"slide0128_image072.gif")
![](3D"slide0128_image073.gif")
![](3D"slide0128_image074.gif")
![](3D"slide0128_image075.gif")
![](3D"slide0128_image076.gif")
![](3D"slide0128_image077.gif")
3
(cis – isomer)*
3-Chloroacrylic Acid Dehalogenase
------=_NextPart_01C49113.DF3ED6A0
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Malonate Semialdehyde Decarboxylase=
and
c-CaaD 149 PVYMVYVSQD--RLTPSAKHAVAKAITDAHRGL-----TGTQH=
FLAQVNFQEQPAGNVFLG----GVQQG-GDTIFVHt-CaaDa 75
-------------------------------------------------------------------=
------PMISCt-CaaDb 70 PFIECHIAT---GLSVARKQQLIRDVIDVTNKS-----IGSDPKIINVLLVEHAEA---------NMSIS-GR-----
MSAD_Psepa 129 PLLKFDIFY---GRTDAQIKSLLDAAHGAMVDA-----FGVPANDRYQTVSQHRPGEMVLE----DTGLGYGRSSAVV
c-CaaD GLHREGR<=
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VIREGSGINFVEHGEHLPDYVPGNANDKALIAKLK-----------t-CaaDb
IHGEAASTERTPAVS----------------------------------------------------=
----------------MSAD_Psepa LLTVISRPRSEEQKVCFYKLLTGALERDCGISPDDVIVALVENSDADWSFGRGRAEFLTGDLV---=
-----------------
*(P. cichorii <=
/span>170
– has both cis and trans specific 3-chloroacrylic acid dehalogenases=
)
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